Eco-Friendly Superhydrophobic Coupling Conversion Coating with Corrosion Resistance on Magnesium Alloy.

An eco-friendly superhydrophobic conversion coating is fabricated to enhance the corrosion resistance of the AZ31B Mg alloy by combining the deep eutectic solvent pretreatment and electrodeposition. The coral-like micro-nano structure formed by reacting deep eutectic solvent and Mg alloy provides a structural basis for constructing a superhydrophobic coating. Cerium stearate with low surface energy is deposited on the structure, providing the coating's superhydrophobicity and the corrosion inhibition effect. Electrochemical test results demonstrate that the as-prepared superhydrophobic conversion coating (water contact angle at 154.7°) with a 99.68% protection effect significantly improves anticorrosion properties for the AZ31B Mg alloy. The corrosion current density decreases from 1.79 × 10-4 A·cm-2 of Mg substrate to 5.57 × 10-7 A·cm-2 of the coated sample. Besides, the electrochemical impedance modulus reaches the value of 1.69 × 103 Ω·cm2 and increases approximately 23 times in magnitude compared with the Mg substrate. Furthermore, the corrosion protection mechanism is attributed to the coupling effect of water-repellency barrier protection and corrosion inhibition, resulting in excellent corrosion resistance. Results demonstrate a promising strategy for the corrosion protection of Mg alloys by replacing the chromate conversion coating with the superhydrophobic coupling conversion coating.

Microskeleton Magnetic Nanofiller Composite with Highly Reliable Superhydrophobic Protection for Long-Lived Electromagnetic Interface Shielding.

Superhydrophobic/electromagnetic interference (EMI) shielding materials have received a great deal of attention, attributing to their excellent water repellence characteristic. However, it is really challenging to simultaneously achieve materials with superhydrophobicity, high EMI shielding performance, and long-term stability of these materials that can operate around the clock in harsh service conditions. Herein, a novel strategy to create an integrated microskeleton magnetic nanofiller composite (IMMNC) with exceptional liquid repellency, enhanced EMI shielding effectiveness, and extreme environment reliability is reported. The superhydrophobicity of the IMMNC was maintained after extreme mechanical and chemical damage due to the synergistic enhancement between epoxy-silicone oligomers/polymerized rosin and microskeleton. Consecutively hierarchical micro/nanoarchitectures and conductive pathways endow the IMMNC with a high EMI shielding effectiveness up to 80.7 dB and a satisfactory antifouling capacity for solid and water-based contaminants. More interestingly, this composite still maintains a superior EMI shielding performance after being subjected to ultrasonic vibration, low (-20 °C) or high temperature (300 °C), and even strong acid (1 M), demonstrating its great potential and reliability as a high-performance EMI shielding material resistant to harsh operating conditions. This work provides an efficient and practical solution for developing next-generation EMI shielding materials with high reliability in an all-weather complex and changeable environment.

Impact of Atomization Pressure on the Particle Size of Nickel-Based Superalloy Powders by Numerical Simulation.

Vacuum induction melting gas atomization (VIGA) has evolved as an important production technique of superalloy powders used in additive manufacturing. However, the development of powder preparation techniques is limited because the crushing process of gas-atomized metal melt is difficult to characterize by conventional experimental methods. Herein, we report the application of computational fluid dynamics to simulate the breaking behavior of droplets in the process of preparing nickel-based superalloy powders by VIGA, as well as the results on the effect of gas pressure on the atomization process and powder particle size distribution of metal melt. In the process of primary atomization, the crushing morphology of superalloy melt shows an alternate transformation of umbrella shapes and inverted mushroom cloud shapes, and with the increase in atomization pressure, the disorder of the two-phase flow field increases, which is conducive to sufficient breakage of the melt. Most importantly, in the process of secondary atomization and with the increasing atomization pressure, the particle size distribution becomes narrower, the median particle diameter and average particle size decrease, and the decreasing trend of the particle size increases gradually. The simulation results are compliant with the performed nickel-based superalloy powder preparation tests. This study provides insight into the production and process optimization of superalloy powder prepared by the VIGA method.

Sandpaper as template for a robust superhydrophobic surface with self-cleaning and anti-snow/icing performances.

Superhydrophobic surfaces have important applications in various fields. However, the development of artificial superhydrophobic surfaces for large scale applications is hindered by their poor mechanical and chemical robustness. In this study, a simple, inexpensive, and scalable strategy was reported to create a versatile superhydrophobic surface that used sandpaper as a template to lock-in the fluorinated inorganic/organic film. The surface exhibited exceptional mechanical robustness, pressure stability, and repellency to hot water. Moreover, the surface could be widely stuck to any substrate by using a double-sided adhesive or glue. Interestingly, the surface with superamphiphobic properties exhibited superior self-cleaning and anti-snow/icing performance even after its top layer was exposed to 50 abrasion cycles with sandpaper. Besides, it had excellent repellency to corrosive liquids and substances with low-surface-energy. We envision that the superhydrophobic sandpaper surface will have a potential application in infrastructure and medicine, and can also behave as an effective antifouling and anti-snow/icing material operating in harsh environments.

Rough Structure of Electrodeposition as a Template for an Ultrarobust Self-Cleaning Surface.

Superhydrophobic surfaces with self-cleaning properties have been developed based on roughness on the micro- and nanometer scales and low-energy surfaces. However, such surfaces are fragile and stop functioning when exposed to oil. Addressing these challenges, here we show an ultrarobust self-cleaning surface fabricated by a process of metal electrodeposition of a rough structure that is subsequently coated with fluorinated metal-oxide nanoparticles. Scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction were employed to characterize the surfaces. The micro- and nanoscale roughness jointly with the low surface energy imparted by the fluorinated nanoparticles yielded surfaces with water contact angle of 164.1° and a sliding angle of 3.2°. Most interestingly, the surface exhibits fascinating mechanical stability after finger-wipe, knife-scratch, sand abrasion, and sandpaper abrasion tests. It is found that the surface with superamphiphobic properties has excellent repellency toward common corrosive liquids and low-surface-energy substances. Amazingly, the surface exhibited excellent self-cleaning ability and remained intact even after its top layer was exposed to 50 abrasion cycles with sandpaper and oil contamination. It is believed that this simple, unique, and practical method can provide new approaches for effectively solving the stability issue of superhydrophobic surfaces and could extend to a variety of metallic materials.